EFFECT OF ANIONIC SURFACTANT ADDITIVES ON THE SURFACE CHARACTERISTICS OF SOLUTIONS OF DICATIONIC DIIMIDAZOLIUM SURFACTANTS WITH SHORT SPACERS FRAGMENTS
- Авторлар: Khil’ko S.L.1, Kotenko A.A.1
-
Мекемелер:
- Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry
- Шығарылым: Том 87, № 5 (2025)
- Беттер: 563-574
- Бөлім: Articles
- ##submission.dateSubmitted##: 02.12.2025
- ##submission.datePublished##: 15.09.2025
- URL: https://gynecology.orscience.ru/0023-2912/article/view/697455
- DOI: https://doi.org/10.7868/S3034543X25050066
- ID: 697455
Дәйексөз келтіру
Аннотация
Tensionetric and dilatational rheological characteristics of solutions of dicationic diimidazolium surfactants mixtures with extremely short spacer fragments and anionic surfactants (sodium dodecyl sulfate, sulfonol, sodium 3-laureth sulfate) at the interface with air were studied using the pendant drop and oscillating drop methods. The nature of interaction between dicationic and anionic surfactants depends on the structure of the anionic surfactant molecules. The possibility of forming strong complexes between a dicationic surfactant with 4 methylene groups in the spacer fragment and sodium dodecyl sulfate with the component ratio close to 1 : 1 was shown. It was found that the resulting complexes are stable in the neutral and slightly acidic pH range.
Авторлар туралы
S. Khil’ko
Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry
Email: sv-hilko59@yandex.ru
Donetsk, Russia
A. Kotenko
Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry
Email: email@example.com
Donetsk, Russia
Әдебиет тізімі
- Mehan S., Aswal V.K., Kohlbrecher J. Cationic versus anionic surfactant in tuning the structure and interaction of nanoparticle, protein, and surfactant complexes // Langmuir. 2014. V. 30. № 33. Р. 9941–9950. https://doi.org/10.1021/la502410v
- Koehler R.D., Raghavan S.R, Kaler E.W. Microstructure and dynamics of wormlike micellar solutions formed by mixing cationic and anionic surfactants // J. Phys. Chem. B. 2000. V. 104. № 47. Р. 11035–11044. https://doi.org/10.1021/jp0018899
- O’Lenick A.J. Anionic / cationic surfactant complexes // Cosmetics and Toiletries. 2005. V. 120. № 11. Р. 63–64. https://doi.org/10.13140/RG.2.1.3084.2082
- Mucic N., Skrbic J., Bucko S., Petrovic L., Katona J., Fainerman V.B., Aksenenko E.V., Schneck E., Miller R. Adsorption of equimolar mixtures of cationic and anionic surfactants at the water/hexane interface // Colloids Interfaces. 2021. V. 5. № 1. Р. 1–16. https://doi.org/10.3390/colloids5010001
- Богданова Ю.Г., Должикова В.Д., Сумм Б.Д. Влияние химической природы компонентов на смачивающее действие растворов смесей поверхностно-активных веществ // Вестн. Моск. ун-та. Сер. 2. Химия. 2004. Т. 45. № 3. С. 186–194.
- La Mesa C., Risuleo G. Surface activity and efficiency of cat-anionic surfactant mixtures // Front. Chem. 2021. V. 9. Р. 790873. https://doi.org/10.3389/fchem.2021.790873
- Холмберг К., Йёнссон Б., Кронберг Б., Линдман Б. Поверхностно-активные вещества и полимеры в водных растворах. Пер. с англ. М.: БИНОМ. Лаборатория знаний. 2007. 526 с.
- Семьянова Д.В., Кондратьев С.А. Обоснование применения параметра взаимодействия при выборе комбинации флотационных реагентов // Физико‑технические проблемы разработки полезных ископаемых. 2024. № 6. С. 139–147. https://doi.org/10.15372/FTPRPI20240615
- Опанасенко О.Н., Крутько Н.П., Жигалова О.Л., Лукша О.В., Козинец Т.А. Стабилизация нефтяных дисперсий композициями поверхностно-активных веществ // Доклады Национальной академии наук Беларуси. 2017. Т. 61. № 1. С. 47–53.
- Rosen M.J., Kunjappu J.T. Surfactants and interfacial phenomena // John Wiley & Sons Ltd.: New York. 2012. 616 р.
- Menger F.M., Keiper J.S., Azov V. Gemini surfactants with acetylenic spacers // Langmuir. 2000. V. 16. № 5. Р. 2062–2067. https://doi.org/10.1021/LA9910576
- Hait S.K., Moulik S.P. Gemini surfactants: A distinct class of self assembling molecules // Current Science. 2002. V. 82. № 9. P. 1101–1111.
- Sekhon B.S. Gemini (dimeric) Surfactants. The two-faced molecules // Resonance. 2004. V. 9. № 3. P. 42–49. https://doi.org/10.1007/BF02834987
- Kamal M.S. A review of gemini surfactants: potential application in enhanced oil recovery // Journal of Surfactants and Detergents. 2016. V. 19. № 2. Р. 223–236. https://doi.org/10.1007/s11743-015-1776-5
- Menger F.M., Keiper J. Gemini surfactants // Angew. Chem. Int. Ed. 2000. V. 39. № 11. P. 1906–1920. https://doi.org/10.1002/1521-3773(20000602)39:11%3C1906::AID-ANIE1906%3E3.0.CO;2-Q
- Tariq M., Freire M.G., Saramago B., Coutinho J.A.P., Canongia Lopes J.N., Rebelo L.P.N. ChemInform abstract: Surface tension of ionic liquids and ionic liquid solutions // Chemical Society Reviews. 2012. V. 43. № 18. Р. 829–868. https://doi.org/10.1002/chin.201218261
- Shukla D., Tyagi V.K. Cationic gemini surfactants: A review // J. Oleo Science. 2006. V. 55. № 8. Р. 381–390. https://doi.org/10.5650/jos.55.381
- Karthaus O., Shimomura M., Hioki M., Tahara R., Nakamura H. Reversible photomorphism in surface monolayers // J. Am. Chem. Soc. 1996. V. 118. № 38. Р. 9174–9175. https://doi.org/10.1021/ja9614272
- Ao M., Xu G., Zhu Y., Bai Y. Synthesis and properties of ionic liquid-type Gemini imidazolium surfactants // J. Colloid. Interface Sci. 2008. V. 326. № 2. Р. 490–495. https://doi.org/10.1016/j.jcis.2008.06.048
- Ren C., Wang F., Zhang Z., Nie H., Li N., Cui M. Synthesis, surface activity and aggregation behavior of Gemini imidazolium surfactants 1,3-bis(3-alkylimidazolium-1-yl) propane bromide // Colloids Surf. A. 2015. V. 467. P. 1–8. https://doi.org/10.1016/j.colsurfa.2014.11.031
- Zabolotniy A.A., Trush E.N., Zarechnaya O.M., Mikhailov V.A. Dicationic bis-imidazoliums as a platform for ionic liquids: Long tails and short spacers // Journal of Ionic Liquids. 2022. V. 2. № 2. 100045. https://doi.org/10.1016/j.jil.2022.100045
- Котенко А.А., Хилько С.Л. Поверхностные свойства растворов дикатионных имидазолиевых ПАВ с короткими мостиковыми фрагментами // Коллоид. журн. 2021. Т. 83. № 2. С. 179–186. https://doi.org/10.31857/S0023291221020051
- Loglio G., Pandolfini P., Miller R. Novel methods to study interfacial layers // Amsterdam: Elsevier. 2001. V. 11. Р. 439–446.
- Zholob S.A., Makievski A.V., Miller R., Fainerman V.B. Optimisation of calculation methods for determination of surface tensions by drop profile analysis tensiometry // Adv. Colloid Interface Sci. 2007. V. 134–135. P. 322–329. https://doi.org/10.1016/j.cis.2007.04.011
- Tomasic V., Stefanic I., Filipovic-Vincekovic N. Adsorption, association and precipitation in hexadecyltrimethylammonium bromide/sodium dodecyl sulfate mixtures // Colloid. Polym. Sci. 1999. V. 277. P. 153–163. https://doi.org/10.1007/s003960050380
- Cui Z.G., Canselier J.P. Interfacial and micellar properties of some anionic/cationic binary surfactant systems. 1. Surface properties and prediction of surface tension // Colloid Polym. Sci. 2000. V. 278. P. 22–29. https://doi.org/10.1007/s003960050004
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