Reaction of Technetium(I) Tricarbonyl Hexafluoroacetylacetonate Complexes with CCl4: Formation and Crystal Structure of [99ТсСl(СО)3(РРh3)2] Stereoisomers and of fac-[99ТсСl(СО)3(С5Н5N)2]

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Рұқсат ақылы немесе тек жазылушылар үшін

Аннотация

In the course of prolonged interaction in the system consisting of [99Тс(hfa)(СО)4] (hfa is the anion of 1,1,1,5,5,5-hexafluoroacetylacetone), triphenylphosphine (РРh3) or pyridine (py), and CCl4, the hfa anion is gradually displaced by the chloride ion with the formation of the complexes fac- and mer-[99ТсСl(СО)3(РРh3)2] and fac-[99ТсСl(СО)3(py)2]. The crystal and molecular structures of the complexes were determined. The complex fac [99ТсСl(СО)3(РРh3)2] is the first structurally confirmed example of technetium(I) tricarbonyl bis(triphenylphosphine) complexes of facial structure.

Авторлар туралы

G. Sidorenko

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI

Email: gevasid@mail.ru
St. Petersburg, Russia; Ozyorsk, Russia

V. Gurzhiy

St. Petersburg State University

St. Petersburg, Russia

A. Miroslavov

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI; St. Petersburg State University

St. Petersburg, Russia; Ozyorsk, Russia; St. Petersburg, Russia

A. Kochergina

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI; St. Petersburg State University

St. Petersburg, Russia; Ozyorsk, Russia; St. Petersburg, Russia

M. Tyupina

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI

St. Petersburg, Russia; Ozyorsk, Russia

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