Reaction of Technetium(I) Tricarbonyl Hexafluoroacetylacetonate Complexes with CCl4: Formation and Crystal Structure of [99ТсСl(СО)3(РРh3)2] Stereoisomers and of fac-[99ТсСl(СО)3(С5Н5N)2]

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In the course of prolonged interaction in the system consisting of [99Тс(hfa)(СО)4] (hfa is the anion of 1,1,1,5,5,5-hexafluoroacetylacetone), triphenylphosphine (РРh3) or pyridine (py), and CCl4, the hfa anion is gradually displaced by the chloride ion with the formation of the complexes fac- and mer-[99ТсСl(СО)3(РРh3)2] and fac-[99ТсСl(СО)3(py)2]. The crystal and molecular structures of the complexes were determined. The complex fac [99ТсСl(СО)3(РРh3)2] is the first structurally confirmed example of technetium(I) tricarbonyl bis(triphenylphosphine) complexes of facial structure.

作者简介

G. Sidorenko

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI

Email: gevasid@mail.ru
St. Petersburg, Russia; Ozyorsk, Russia

V. Gurzhiy

St. Petersburg State University

St. Petersburg, Russia

A. Miroslavov

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI; St. Petersburg State University

St. Petersburg, Russia; Ozyorsk, Russia; St. Petersburg, Russia

A. Kochergina

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI; St. Petersburg State University

St. Petersburg, Russia; Ozyorsk, Russia; St. Petersburg, Russia

M. Tyupina

Khlopin Radium Institute; Ozyorsk Institute of Technology, Branch of National Research Nuclear University MEPhI

St. Petersburg, Russia; Ozyorsk, Russia

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