Colored thermolith sands based on gaize (opoka-like) rocks

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Nowadays, more and more attention is being paid to improving the aesthetic appeal of ceramic face bricks. It is the variety of appearance that influences a consumer’s choice of a face brick particular type. Different variations of the ceramic wall materials face surface are achieved by three main technological methods, which can be easily combined in one product: relief creation on the face surface --> coloring --> shotcreting. The technology of the first two techniques is well developed, but shotcrete causes certain difficulties. The problem is the lack of colored mineral chips. Natural quartz sand, which is white or grayish in color, and some industrial waste, which is gray and black in color, is often used for shotcrete for ceramic bricks. The authors propose to produce textured colored sands on the base of opal-cristobalite rocks – gaizes by saturating them with elements-chromophores salts solutions of different concentrations with the mineralizers introduction and subsequent burning. The gaizes microporous structure promotes gaize grains coloring throughout the entire volume during firing, while the salts and mineralizers introduction promotes intensive sintering. The conducted experiments allowed to obtain colored thermolite sands of different color and grain composition, which can be used not only for ceramic bricks texturing, but also for concrete products shotcreting, decorative plaster mixtures production, mosaic polymer floors, etc.

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作者简介

V. Kotlyar

Don State Technical University

编辑信件的主要联系方式.
Email: diatomit_kvd@mail.ru

Doctor of Sciences (Engineering), Professor

俄罗斯联邦, 1, Gagarina Square, Rostov-on-Don 344003

К. Lapunova

Don State Technical University

Email: keramik_kira@mail.ru

Candidate of Sciences (Engineering)

俄罗斯联邦, 1, Gagarina Square, Rostov-on-Don 344003

А. Zemlyanskaya

Don State Technical University

Email: anna-bondaryuk@yandex.ru

Candidate of Sciences (Engineering)

俄罗斯联邦, 1, Gagarina Square, Rostov-on-Don 344003

参考

  1. Nebezhko Yu.I., Lapunova K.A. Features of the front surface of soft-molded ceramic brick. Collection of materials of the III All-Russian scientific conference “Construction materials science: the present and the future”. Moscow: MSTU. 2023, pp. 204–210. EDN: OPWCDU
  2. Meskhi B.Ch., Bozhko Yu.A., Terekhina Yu.V., Lapunova K.A. Brick-design and its main elements. Stroitel’nye Materialy [Construction Materials]. 2020. No. 8, pp. 47–51. (In Russian). EDN: BKBXAY. https://doi.org/10.31659/0585-430X-2020-783-8-47-51
  3. Stolboushkin A.Yu., Portnov А.О., Akst D.V., Shchetinin D.A., Fomina O.A., Spiridonova I.V. Volume coloring of wall ceramics with additives of associated products from ferrosilicomanganese production. Stroitel’nye Materialy [Construction Materials]. 2023. No. 5, pp. 14–21. (In Russian). EDN: FJKDJN. https://doi.org/10.31659/0585-430X-2023-813-5-14-21
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  6. Bondaryuk A.G. Wall ceramics based on carbonate varieties of opoka-like rocks: Dis. ... Candidate of Sciences (Engineering). Rostov-on-Don. 2010. 140 p. (In Russian). EDN: EDN: OOWJUO
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  11. Lapunova K.A. Technology and design of facing products of wall ceramics based on siliceous opoka-like rocks: Dis. ... Candidate of Sciences (Engineering). Rostov-on-Don. 2013. 193 p. (In Russian). EDN: SUZGUZ
  12. Bozhko Yu.A. Lapunova K.A. Types of the front surface of soft-molded ceramic bricks. In the collection: Actual problems of science and technology. Materials of the national scientific and practical conference / Under the general. Ed. N.A. Shevchenko. 2020, pp. 1644–1647. (In Russian). EDN: YAEIUB

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2. Fig. 1. X-ray of the gaize

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3. Fig. 2. Electron microscope micrographs of the gaize

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4. Fig. 3. Thermolite sand based on natural gaize at a firing temperature of 900–1100оC

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5. Fig. 4. Thermolite sand based on gaize, saturated with salts: а – manganese; b – copper; c – cobalt

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6. Fig. 5. Thermolite sand of different colors on the surface of the brick: а – white; b – brown

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7. Fig. 6. Colored thermolith sand on the surface of the brick with a coating of low-melting colorless glaze

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8. Fig. 7. The surface of the brick, textured fragmentally with colored thermolith sand coated with a fusible colorless glaze

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