Decomposition features and mechanical properties of aging Ti49Ni51 alloy with shape memory effects subjected to heat treatment

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅存取

详细

The features of the microstructure of the Ti–51 at.%Ni shape memory alloy have been studied after aging at various temperatures. In combination with studies using optical and electron microscopy and X-ray analysis, mechanical properties were tested for tensile strength at room temperature. It has been established that the aged alloy is distinguished by a high level of mechanical properties (tensile strength up to 1200 MPa with a relative elongation of up to 35 %) due to highly dispersed homogeneous decomposition and the effect of simultaneous hardening and increased plasticity as a result of deformation-induced martensitic transformation.

全文:

受限制的访问

作者简介

N. Kuranova

Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences; Ural Federal University

Email: pushin@imp.uran.ru
俄罗斯联邦, Ekaterinburg, 620108; Ekaterinburg, 620002

V. Makarov

Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences

Email: pushin@imp.uran.ru
俄罗斯联邦, Ekaterinburg, 620108

V. Pushin

Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences; Ural Federal University

编辑信件的主要联系方式.
Email: pushin@imp.uran.ru
俄罗斯联邦, Ekaterinburg, 620108; Ekaterinburg, 620002

参考

  1. Ооцука К., Симидзу К., Судзуки Ю., Сэкигути Ю., Тадаки Ц., Хомма Т., Миядзаки С. Сплавы с эффектом памяти формы. М.: Металлургия, 1990. 224 c.
  2. Duering T.W., Melton K.L., Stockel D., Wayman C.M. (Eds.) Engineering Aspects of Shape Memory Alloys. Butterworth-Heineman: London, UK. 1990. 512 p.
  3. Хачин В.Н., Пушин В.Г., Кондратьев В.В. Никелид титана. Структура и свойства. М.: Наука, 1992. 159 c.
  4. Pushin V.G. Alloys with a Thermomechanical Memory: Structure, Properties, and Application // Phys. Met. Metall. 2000. V. 90. Suppl. 1. P. S68–S95.
  5. Brailovski V., Khmelevskaya I.Yu., Prokoshkin S.D., Pushin V.G., Ryklina E.P., Valiev R.Z. Foundation of heat and thermomechanical treatments and their on the structure and properties of titanium nickelide-based alloys // Phys. Met. Metal. 2004. V. 97. Suppl. 1. P. S3–S55.
  6. Razov A.I. Application of titanium nickelide-based alloys in engineering // Phys. Met. Metal. 2004. V. 97. Suppl. 1. P. S97–S126.
  7. Bonnot E., Romero R., Mañosa L., Vives E., Planes A. Elastocaloric effect associated with the martensitic transition in shape-memory alloys // Phys. Rev. Lett. 2008. V. 100. P. 125901.
  8. Cui J. Shape memory alloys and their applications in power generation and refrigeration / In Mesoscopic phenomena in multifunctional materials. Eds. A. Saxena, A. Planes. Germany: Springer, 2014. P. 289–307.
  9. Prokoshkin S.D., Pushin V.G., Ryklina E.P., Khmelevskaya I.Yu. Application of Titanium Nickelide–based Alloys in Medicine // Phys. Met. Metal. 2004. V. 97. P. S56–S96.
  10. Wilson J., Weselowsky M. Shape Memory Alloys for Seismic Response Modification: A State-of-the-Art Review // Earth. Spectra. 2005. V. 21. P. 569–601.
  11. Yoneyama T., Miyazaki S. Shape Memory Alloys for Biomedical Applications. Wordhead Publishing: Cambridge, UK. 2009. 320 p.
  12. Dong J., Cai C., O’Keil A. Overview of Potential and Existing Applications of Shape Memory Alloys in Bridges // J. Bridg. Eng. 2011. V. 16. P. 305–315.
  13. Pushin V., Kuranova N., Marchenkova E., Pushin A. Design and Development of Ti–Ni, Ni–Mn–Ga and Cu–Al–Ni-based Alloys with High and Low Temperature Shape Memory Effects // Materials. 2019. № 12. P. 2616 (24 pages).
  14. Kuranova N.N., Makarov V.V., Pushin V.G., Ustyugov Y.M. Influence of Heat Treatment and Deformation on the Structure, Phase Transformation, and Mechanical Behavior of Bulk TiNi-Based Alloys // Metals. 2022. V. 12. P. 2188.
  15. Пушин В.Г., Прокошкин С.Д., Валиев Р.З., Браиловский В., Валиев Э.З., Волков А.Е., Глезер А.М., Добаткин С.В., Дударев В.Ф., Жу Ю.Т., Зайнулин Ю.Г., Колобов Ю.Р., Кондратьев В.В., Королев А.В., Коршунов А.И., Коуров Н.И., Кудреватых Н.В., Лотков А.И., Мейснер Л.Л., Попов А.А., Попов Н.Н., Разов А.И., Хусаинов М.А., Чумляков Ю.И., Андреев С.В., Батурин А.А., Беляев С.П., Гришков В.Н., Гундеров Д.В., Дюпин А.П., Иванов К.В., Итин В.И., Касымов М.К., Кашин О.А., Киреева И.В., Козлов А.И., Кунцевич Т.Э., Куранова Н.Н., Пушина Н.Ю., Рыклина Е.П., Уксусников А.Н., Хмелевская И.Ю., Шеляков А.В., Шкловер В.Я., Шорохов Е.В., Юрченко Л.И. Сплавы никелида титана с памятью формы. Ч.I. Структура, фазовые превращения и свойства. Екатеринбург: УрО РАН, 2006. 440 с.
  16. Куранова Н.Н., Макаров В.В., Пушин В.Г. Влияние механо-термической обработки на структуру и механические свойства сплава Ti49.5Ni50.5 с эффектами памяти формы // ФММ. 2022. Т. 123. № 10. С. 1063–1071.
  17. Куранова Н.Н., Макаров В.В., Пушин В.Г., Попов Н.А. Структура и механические свойства стареющего сплава Ti49Ni51 с эффектами памяти формы после механо-термической обработки // ФММ. 2023. Т. 124. № 2. С. 239–247.
  18. Пушин В.Г., Волкова С.Б., Матвеева Н.М., Юрченко Л.И., Чистяков А.С. Структурные и фазовые превращения в квазибинарных сплавах системы TiNi-TiCu, быстрозакаленных из расплава. IV. Микроструктура кристаллических сплавов // ФММ. 1997. Т. 83. № 6. С. 149–156.
  19. Miyazaki S., Ishida A. Martensitic transformation and shape memory behavior in sputter-deposited TiNi-base thin films // Mater. Sci. and Eng. 1999. V. A273–275. P. 106–133.
  20. Fu Y., Du H., Huang W., Zhang S., Hu M. TiNi-based thin films in MEMS applications: A review // Sens.Actuators A. 2004. V. 112. P. 398–408.
  21. Пушин А.В., Попов А.А., Пушин В.Г. Влияние отклонения химического состава от стехиометричского на структурные и фазовые превращения и свойства быстрозакаленных сплавов Ti50+xNi25-xCu25 // ФММ. 2012. Т. 113. № 3. С. 299–311.
  22. Pushin V.G., Stolyarov V.V., Valiev R.Z., Kourov N.I., Kuranova N.N., Prokofiev E.A., Yurchenko L.I. Features of Structure and Phase Transformations in Shape Memory TiNi-Based Alloys after Severe Plastic Deformation // Ann. Chim. Sci. Mat. 2002. V. 27. P. 77–88.
  23. Pushin V.G., Valiev R.Z., Zhu Y.T., Gunderov D.V., Kourov N.I., Kuntsevich T.E., Uksusnikov A.N., Yurchenko L.I. Effect of Severe Plastic Deformation on the Behavior of Ti–Ni Shape Memory Alloys // Mater. Trans. 2006. V. 47. P. 694–697.
  24. Valiev R., Gunderov D., Prokofiev E., Pushin V., Zhu Yu. Nanostructuring of TiNi alloy by SPD processing for advanced properties // Mater. Trans. 2008. V. 49. P. 97–101.
  25. Куранова Н.Н., Гундеров Д.В., Уксусников А.Н., Лукьянов А.В., Юрченко Л.И., Прокофьев Е.А., Пушин В.Г., Валиев Р.З. Влияние термообработки на структурные и фазовые превращения и механические свойства сплава TiNi, подвергнутого интенсивной пластической деформации кручением // ФММ. 2009. Т. 108. № 6. С. 589–601.
  26. Ren X., Miura N., Zhang J., Otsuka K., Tanake K., Koiwa M., Suzuki N., Chumlykov Y.I. A Comparative Study of Elastic Constants of Ti-Ni-based Alloys Prior to Martensitic Transformation // Mater. Sci. Eng. 2001. V. A312. P. 196–206.
  27. Лободюк В.А., Коваль Ю.Н., Пушин В.Г. Кристаллоструктурные особенности предпереходных явлений и термоупругих мартенситных превращений в сплавах цветных металлов // ФММ. 2011. Т. 111. № 2. С. 169–194.
  28. Sarkar S., Ren X., Otsuka K. Evidence for strain glass in the ferroelastic-martensitic system Ti50-xNi50+x // Phys. Rev. Lett. 2005. V. 95. P. 205702.
  29. Jin Y.M., Wang Yu.U., Ren. Y. Theory and experimental evidence of phonon domains and their roles in pre-martensitic phenomena // Computational Mater. 2015. V. 1. P. 15002.
  30. Wang Y., Jin Y.M. Martensitic transformation precursors: phonon theory and critical experiments / Proc. Int. Conf. Solid-solid phase transformations in inorganic materials. 2015. P. 467–474.
  31. Ko W.S., Maisel S.B., Grabowski B., Jeon J.B., Neugebauer J. Atomic scale processes of phase transformations in nanocrystalline NiTi shape-memory alloys // Acta Mater. 2017. V. 123. P. 90–101.
  32. Deng Z., Li Q., Onuki Y., Sun Q. Multifunctional nanostructured NiTi alloy with invar, elinvar and rinvar properties // J. Alloys Comp. 2022. V. 909. P. 164682.
  33. Xu K., Luo J., Li C., Shen Y., Li C., Ma X., Li M. Mechanisms of stress-induced martensitic transformation and transformation-induced plasticity in NiTi shape memory alloy related to superelastic stability // Scripta Mater. 2022. V. 217. P. 114775.

补充文件

附件文件
动作
1. JATS XML
下载
2. Fig. 1. Light-field (a, b) TEM images of the microstructure and corresponding microelectronograms (O. Z. [100]B2 (c), O. Z. [111]B2 (d)) of Ti49Ni51 alloy in the initial quenched state.

下载 (29KB)
索引源数据
3. Fig. 2. Light-field (a, c) TEM images of the microstructure of Ti49Ni51 alloy after quenching from 1073 K into water and PIO 473 K for one hour, the corresponding microelectronogram (b, O. Z. [100]B2) and a scheme for decoding satellite effects of diffuse scattering in this section (d).

下载 (29KB)
索引源数据
4. Fig. 3. Light (a, c) and dark–field (d) - in the 110B2 matrix reflex on microelectronogram 3b, TEM images of the microstructure and the corresponding microelectronogram (b, O. Z. [001]B2) of Ti49Ni51 alloy after PIO at 573 K for 1 hour.

下载 (46KB)
索引源数据
5. Fig. 4. Light (a) and dark (b) – in three reflexes indicated by a ring on the microelectronogram 4b, TEM images of the microstructure and the corresponding microelectronogram (c, O. Z. [115]B2) of Ti49Ni51 alloy after PIO at 623 K for 1 hour.

下载 (38KB)
索引源数据
6. Fig. 5. Light (a) and dark-field (b, c) in the reflexes indicated by numbers 1 and 2 on the 5g microelectronogram, TEM images of the microstructure and the corresponding microelectronogram (g, O. Z. [110]B2) of Ti49Ni51 alloy after PIO at 673 K for 1 hour.

下载 (35KB)
索引源数据
7. Fig. 6. Light–field (a-b) TEM images of the microstructure and the corresponding microelectronogram (g, O. Z. [120]B2) of Ti49Ni51 alloy after PIO at 773 K for 1 hour.

下载 (37KB)
索引源数据
8. Fig. 7. Light–field (a-c) TEM images of the microstructure and the corresponding microelectronogram (g, O. Z. [331]B2) of Ti49Ni51 alloy after PIO at 773 K for 2 (a, b). 5 h (c).

下载 (43KB)
索引源数据
9. Fig. 8. Dependences of the tensile strengths σB, dislocation σ0.2 and phase σM of yield strength and elongation δ on the aging temperature of the hardened alloy Ti49Ni51.

下载 (11KB)
索引源数据
10. Fig. 9. Fractography alloys4951 then tempering from 1173 K (A) and Pio at 673 K, 1 h (b).

下载 (22KB)
索引源数据