Замещенные цеолиты ZSM‑22: Сравнение физико-химических и каталитических свойств (обзор)

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Abstract

In this review, a comparative analysis of the literature on the synthesis, physicochemical, and catalytic properties of substituted ZSM-22 zeolites is presented. The physicochemical characteristics of Ce, Fe, Ga, B, and V substituted ZSM-22 samples are compared with those of the parent analog based on X-ray phase analysis, transmission electron microscopy, scanning electron microscopy, low-temperature nitrogen adsorption-desorption, FTIR spectroscopy of adsorbed pyridine, UV spectroscopy, X-ray photoelectron spectroscopy, temperature-programmed desorption of ammonia, and others. The possibility of using substituted ZSM-22 zeolites in the reactions of hydroisomerization of long-chain hydrocarbons, isomerization of butenes, methanol conversion to olefins, decomposition of nitrous oxide, disproportionation of ethylbenzene, and hydroxylation of arenes to phenols is demonstrated.

About the authors

V. A. Ostroumova

Institute of Petrochemical Synthesis named after A. V. Topchieva of RAS

Author for correspondence.
Email: ostroumova@ips.ac.ru
Moscow, 119991 Russia

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