Synthesis and Functionalization of Unsymmetrical Terbium(III) Bis-Phthalocyaninates, Promising Components of Hybrid Magnetic Materials
- Authors: Yagodin A.V.1, Kormshchikov I.D.2, Martynov A.G.1, Gorbunova Y.G.1,3, Tsivadze A.Y.1,3
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Affiliations:
- Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
- Faculty of Chemistry, Moscow State University
- Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
- Issue: Vol 68, No 9 (2023)
- Pages: 1146-1153
- Section: КООРДИНАЦИОННЫЕ СОЕДИНЕНИЯ
- URL: https://gynecology.orscience.ru/0044-457X/article/view/666208
- DOI: https://doi.org/10.31857/S0044457X23600706
- EDN: https://elibrary.ru/WRKOIB
- ID: 666208
Cite item
Abstract
A new unsymmetrical terbium bis-Phthalocyaninate Tb(A7B) with one terminal aliphatic OH group was obtained by template cross-condensation of diethoxyphthalonitrile (A) and phthalonitrile (B) functionalized with diethylene glycol moiety. The subsequent functionalization of the complex included the successive replacement of this OH group by the iodide and thioacetate substituents. The synthesized complexes can act as components of hybrid materials upon immobilization on surfaces of various nature.
About the authors
A. V. Yagodin
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: martynov@phyche.ac.ru
119071, Moscow, Russia
I. D. Kormshchikov
Faculty of Chemistry, Moscow State University
Email: martynov@phyche.ac.ru
119991, Moscow, Russia
A. G. Martynov
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences
Email: martynov@phyche.ac.ru
119071, Moscow, Russia
Yu. G. Gorbunova
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences; Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Email: martynov@phyche.ac.ru
119071, Moscow, Russia; 119991, Moscow, Russia
A. Yu. Tsivadze
Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences; Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Author for correspondence.
Email: martynov@phyche.ac.ru
119991, Moscow, Russia; 119991, Moscow, Russia
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