Crystal structures and properties of metal-organic coordination polymers of the [Zn2(BDC)X (BDC-I)(2–X)DABCO] series

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Resumo

New mixed-ligand organometallic coordination polymers based on zinc terephthalate (bdc), 2-iodoterephthalate (bdc-I) and 1,4-diazabicyclo[2.2.2]octane (dabco) were obtained: [Zn2(bdc)1.67(bdc-I)0.33dabco] (I), [Zn2(bdc)1.46(bdc-I)0.54dabco] (II), [Zn2(bdc)1.12(bdc-I)0.88dabco] (III), [Zn2(bdc)0.80(bdc-I)1.2dabco] (IV), [Zn2(bdc)0.46(bdc-I)1.54dabco] (V). Their structure and composition were determined by X-ray diffraction, X-ray phase, and elemental analysis. Compounds I–V are isostructural with [Zn2(bdc)2(dabco)], but not with [Zn2(bdc-I)2(dabco)], which we have not described previously, which is confirmed by X-ray phase analysis data. Experiments on the sorption of diiodine vapors are consistent with the idea that the presence of a larger amount of 2-iodoterephthalate in the MOF should lead to a decrease in pore volume: the greatest amount of I2 is absorbed by I, and the smallest by V.

Sobre autores

A. Zaguzin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia

Y. Zaitsev

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State Technical University

Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia; Karl Marx Avenue 20, Novosibirsk, 630073 Russia

A. Zaitsev

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia; Pirogova 1, Novosibirsk, 630090 Russia

N. Korobeynikov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia

M. Bondarenko

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia

E. Maksimovskii

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia

V. Fedin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences

Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia

S. Adonin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences; Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Autor responsável pela correspondência
Email: zaguzin@niic.nsc.ru
Academician Lavrentiev Avenue 3, Novosibirsk, 630090 Russia; Favorsky 1, Irkutsk, 664033 Russia

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