Nickel(II) and Copper(II) Dicyanoargentate Complexes with Ethylenediamine and 4,4´-Bipyridyl Ligands

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The reactions of an aqueous solution of potassium dicyanoargentate with a mixture of nickel(II) or copper(II) chloride and ethylenediamine or 4,4´-bipyridyl in ethanol afford coordination polymers [Ni(En)2(Ag(CN)2)][Ag(CN)2] (I), [Cu(En)2(Ag(CN)2)][Ag(CN)2] (II), and [Cu(4,4´-Bipy)2(Ag(CN)2)2] (III) characterized by XRD (CIF files CCDC nos. 2225984 (I), 2214320 (II), and 2229270 (III)) and IR spectroscopy. According to the XRD data, the crystals of complexes I and II are formed by 1D chains {··NC– Ag–CN–M(En)2··}n (M = Ni (I), Cu (II)) linked with each other by the dicyanoargentate anions via argentophilic contacts (Ag···Ag 3.288(8) Å (I), 3.1616(14) Å (II)). The crystal of compound III consists of independent interpenetrating 3D networks built of polymer layers {Cu[Ag(CN)2]2}n bound to each other by the 4,4´-bipyridyl molecules. The bipyridyl linkers connect the Cu centers with the Ag centers of the [Ag(CN)2] anions thus providing the tridentate coordination of the silver atoms. No Ag···Ag interactions are observed in the crystal of complex III.

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D. Pashnin

South Ural State University (National Research University)

Email: Shepher56@gmail.com
俄罗斯联邦, Chelyabinsk

D. Shevchenko

South Ural State University (National Research University)

编辑信件的主要联系方式.
Email: Shepher56@gmail.com
俄罗斯联邦, Chelyabinsk

V. Sharutin

South Ural State University (National Research University)

Email: Shepher56@gmail.com
俄罗斯联邦, Chelyabinsk

O. Sharutina

South Ural State University (National Research University)

Email: Shepher56@gmail.com
俄罗斯联邦, Chelyabinsk

参考

  1. Batten S.R., Champness N.R. // Phil. Trans. R. Soc., A. 2017. V. 375. Art. 20160032. https://doi.org/10.1098/rsta.2016.0032
  2. Furukawa H., Cordova K.E., O´Keeffe M., Yaghi O.M. // Science. 2013. V. 341. № 6149. Art. 1230444. https://doi.org/10.1126/science.1230444
  3. Liu J., Chen L., Cui H., Zhang J. et al. // Chem. Soc. Rev. 2014. V. 43. № 16. P. 6011. https://doi.org/10.1039/C4CS00094C
  4. Zhang H., Cai J., Feng X.-L et al. // Inorg. Chem. Commun. 2002. V. 5. № 9. P. 637. https://doi.org/10.1016/S1387-7003(02)00514-2
  5. Lin Y.-Y., Lai S.-W., Che C.-M et al. // Inorg. Chem. 2005. V. 44. № 5. P. 1511. https://doi.org/10.1021/ic048876k
  6. Marinescu G., Madalan A.M., Andruh M. // J. Coord. Chem. 2015. V. 68. № 3. P. 479. http://doi.org/10.1080/00958972.2014.997721
  7. Wang J.-Y., Zhang L.-Z., Gu W et al. // J. Coord. Chem. 2006. V. 59. № 15. P. 1685. http://doi.org/10.1080/00958970600580142
  8. Wang J.-Y., Gu W., Wang W.-Z et al. // Chin. J. Chem. 2006. V. 24. № 4. P. 493. https://doi.org/10.1002/cjoc.200690095
  9. Baril-Robert F., Li X., Katz M.J et al. // Inorg. Chem. 2011. V. 50. № 1. P. 231. https://doi.org/10.1021/ic101841a
  10. Galet A., Niel V., Muñoz M.C., Real J.A. // J. Am. Chem. Soc. 2003. V. 125. № 47. P. 14224. https://doi.org/10.1021/ja0377347
  11. Wang L.-F., Zhuang W.-M., Huang G.-Z et al. // Chem. Sci. 2019. V. 10. № 32. P. 7496. https://doi.org/10.1039/c9sc02274k
  12. Gural´skiy I.A., Shylin S.I., Golub B.O et al. // New J. Chem. 2016. V. 40. № 11. P. 9012. https://doi.org/10.1039/C6NJ01472K
  13. Arcís-Castillo Z., Muñoz M.C., Molnár G. et al. // Chem. Eur. J. 2013. V. 19. № 21. P. 6851. https://doi.org/10.1002/chem.201203559
  14. Yoshida K., Akahoshi D., Kawasaki T et al. // Polyhedron. 2013. V. 66. P. 252. http://doi.org/10.1016/j.poly.2013.05.003
  15. Liu W., Peng Y.-Y., Wu S.-G. // Angew. Chem. Int. Ed. 2017. V. 56. № 47. P. 14982. http://doi.org/10.1002/anie.201708973
  16. Etaiw S. El-din H., El-bendary M.M. // Inorg. Chim. Acta. 2015. V. 435. P. 167. http://doi.org/10.1016/j.ica.2015.06.020
  17. Karadağ A., Korkmaz N., Aydin A. , Tekin Ş., Yanar Y., Yerli Y., Korkmaz Ş.A et al.. // New J. Chem. 2018. V. 42. № 6. P. 4679. https://doi.org/10.1039/c7nj04796g
  18. Korkmaz N., Karadağ A., Aydin A. et al. // New J. Chem. 2014. V. 38. № 10. P. 4760. https://doi.org/10.1039/c4nj00851k
  19. Korkmaz N. // Turk. J. Chem. 2020. V. 44. № 4. P. 1110. https://doi.org/10.3906/kim-2004-42
  20. Sharutin, V.V. Sharutina O.K., Popkova M.A., et al. Russ. J. Inorg. Chem., 2019, vol. 64, no. 12, p. 1548. https://doi.org/10.1134/S0044457X19120158
  21. Sharutin V.V. and Popkova M.A. Vest. YuUrGU. Ser.Khim., 2019, vol. 11, no. 2, p. 5. https://doi.org/10.14529/chem190201
  22. Popkova M.A. and Sharutin V.V., Vest. YuUrGU. Ser. Khim., 2021, vol. 13, no. 4, p. 110. https://doi.org/10.14529/chem210409
  23. SMART. SAINT-Plus. V. 5.0. Data Collection, Processing Software for the SMART System, Madison (WI, USA): Bruker AXS Inc., 1998.
  24. SHELXTL/PC. V. 5.10. An Integrated System for Solving, Refining, Displaying Crystal Structures from Diffraction Data, Madison (WI, USA): Bruker AXS Inc., 1998.
  25. Dolomanov O.V., Bourhis L.J., Gildea R.J. et al. // J. Appl. Cryst. 2009. V. 42. P. 339. https://doi.org/10.1107/S0021889808042726
  26. Černák J., Chomič J., Gravereau P. et al. // Inorg. Chim. Acta. 1998. V. 281. № 2. P. 134. https://doi.org/10.1016/S0020-1693(98)00156-X
  27. Suárez-Varela J., Sakiyama H., Cano J., Colacio E. // Dalton Trans. 2007. № 2. P. 249. https://doi.org/10.1039/B611684A
  28. Pretsch E., Buhlman P., Affolter C. Structure Determination of Organic Compounds. Tables of Spectral Data. Springer, 2000.
  29. Nawaz S., Ghaffar A., Monim-ul-Mehboob M. et al. // Z. Naturforsch. B. 2007. V. 72. № 1. P. 43. https://doi.org/10.1515/znb-2016-0154
  30. Bondi A. // J. Phys. Chem. 1964. V. 68. № 3. P. 441. https://doi.org/10.1021/j100785a001
  31. Niel V., Muñoz M.C., Gaspar A.B et al. // Chem. Eur. J. 2002. V. 8. № 11. P. 2446. https://doi.org/10.1002/1521-3765(20020603) 8:11<2446::AID-CHEM2446>3.0.CO;2-K
  32. Soma T., Yuge H, Iwamoto T. // Angew. Chem. 1994. V. 106. № 15–16. P. 1746. https://doi.org/10.1002/ange.19941061547

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2. Fig. 1. Structure of a fragment of complex I.

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3. Fig. 2. Spatial organization of complex I (projection along the b axis; hydrogen atoms are not shown).

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4. Fig. 3. Structure of a fragment of complex III.

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5. Fig. 4. Independent interpenetrating 3D polymer networks in the structure of complex III.

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