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Kinetics of Catalytic Oxidation of Oleic Acid Methyl Ester
- Authors: Yhshchenko D.Y.1, Pai Z.P.1, Uchenova U.V.1, Khlebnikova T.B.1
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Affiliations:
- Boreskov Institute of Catalysis SB RAS
- Issue: Vol 64, No 3 (2023)
- Pages: 298-304
- Section: ARTICLES
- URL: https://gynecology.orscience.ru/0453-8811/article/view/660277
- DOI: https://doi.org/10.31857/S0453881123030127
- ID: 660277
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Abstract
The results of studying the kinetics of the reaction of catalytic oxidation of oleic acid methyl ester with hydrogen peroxide in a two-phase system (aqueous phase-organic phase) in the presence of a bifunctional catalyst of the composition [(Octn)3NMe]3{PO4[WO(O2)2]4} are presented. For the selected reaction conditions, the first orders of catalyst, substrate and oxidizer are established. The value of the activation energy for the temperature range 313–353 K is 47 ± 3 kJ/mol, and the pre-exponential multiplier is (6.0 ± 0.3) × 107 L2 mol–2 min–1.
About the authors
D. Yu. Yhshchenko
Boreskov Institute of Catalysis SB RAS
Author for correspondence.
Email: dyy@catalysis.ru
Russia, 630090, Novosibirsk, Ave. Lavrentiev, 5
Z. P. Pai
Boreskov Institute of Catalysis SB RAS
Email: dyy@catalysis.ru
Russia, 630090, Novosibirsk, Ave. Lavrentiev, 5
U. V. Uchenova
Boreskov Institute of Catalysis SB RAS
Email: dyy@catalysis.ru
Russia, 630090, Novosibirsk, Ave. Lavrentiev, 5
T. B. Khlebnikova
Boreskov Institute of Catalysis SB RAS
Email: dyy@catalysis.ru
Russia, 630090, Novosibirsk, Ave. Lavrentiev, 5
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