Defluorination And Other Transformations of Perfluorinated Tetralin, Alkyltetralins and 4-Methyl-1,2-Dihydronaphthalene with Zinc in DMF. Synthesis of Perfluorinated 1-Ethyl- and 1-Methylnaphthalenes

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

The interaction of perfluorotetralin with zinc in DMF followed by the treatment with water gave 1,1,2,2,3,3,4,4,5,6,8-undecafluorotetralin, perfluoro-2,2'-binaphthyl and octafluoronaphthalene. 1,2,3,4,6,7-Hexafluoro-5-(perfluoroethyl)naphthalene and perfluorinated 1-ethyl- and 1-vinylnaphthalenes were obtained from perfluoro-1-ethyltetralin by a similar reaction. Perfluoro-6-methyltetralin under similar conditions formed 1,2,4,5,6,8-hexafluoro-3-(trifluoromethyl)naphthalene and perfluoro-2-methylnaphthalene. The reaction of perfluoro-4-methyl-1,2-dihydronaphthalene with zinc in DMF resulted in the formation of perfluoro-1-methylnaphthalene. When perfluoro-1-ethyltetraline reacted with bromine-activated zinc in DMF, a mixture containing (perfluoro-4-ethylnaphthalene-1-yl)zinc bromide was formed, which was converted into 1,2,3,4,6,7-hexafluoro-5-(perfluoroethyl)naphthalene and perfluoro-4,4'-diethyl-1,1'-binaphthyl under the action of water and CuCl2, respectively.

Толық мәтін

Рұқсат жабық

Авторлар туралы

V. Sinyakov

Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: karpov@nioch.nsc.ru
Ресей, Novosibirsk

T. Mezhenkova

Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: karpov@nioch.nsc.ru
ORCID iD: 0000-0001-9936-0900
Ресей, Novosibirsk

V. Karpov

Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: karpov@nioch.nsc.ru
Ресей, Novosibirsk

Ya. Zonov

Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of Sciences

Email: karpov@nioch.nsc.ru
ORCID iD: 0000-0003-0267-4976
Ресей, Novosibirsk

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