Features of Methyl Methacrylate Polymerization Mediated by Methylene Blue and Ethyl 2-Bromoisobutyrate under Photoirradiation Conditions

Мұқаба

Дәйексөз келтіру

Толық мәтін

Ашық рұқсат Ашық рұқсат
Рұқсат жабық Рұқсат берілді
Рұқсат жабық Тек жазылушылар үшін

Аннотация

Using methyl methacrylate polymerization as an example, the features of polymer synthesis in the presence of the catalytic system [methylene blue + ethyl 2-bromoisobutyrate] at room temperature under visible light irradiation are investigated. The effect of polymerization conditions, including the light irradiation wavelength and various structure activators, on the monomer conversion and molecular weight characteristics of polymers is estimated. It is shown that polymerization can proceed in the controlled mode under mild temperature conditions according to the atom transfer mechanism (Metal Free Atom Transfer Radical Polymerization) to high conversions at low photocatalyst concentrations.

Авторлар туралы

O. Lizyakina

Lobachevsky State University of Nizhny Novgorod

Email: oksana.94.02@mail.ru
603950, Nizhny Novgorod, Russia

L. Vaganova

Lobachevsky State University of Nizhny Novgorod

Email: oksana.94.02@mail.ru
603950, Nizhny Novgorod, Russia

D. Grishin

Lobachevsky State University of Nizhny Novgorod

Хат алмасуға жауапты Автор.
Email: oksana.94.02@mail.ru
603950, Nizhny Novgorod, Russia

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© О.С. Лизякина, Л.Б. Ваганова, Д.Ф. Гришин, 2023