Electron excitation transfer in nanoclusters of colloidal quantum dots InP/ZnS doped with manganese ions

Cover Page

Cite item

Full Text

Open Access Open Access
Restricted Access Access granted
Restricted Access Subscription Access

Abstract

Colloidal indium phosphide quantum dots with a thin shell of zinc sulfide doped with manganese have been synthesized. Nanoclusters were fabricated based on the obtained nanocrystals. The effect of doping of nanocrystals on the process of Förster resonance transfer of electronic excitation and the spectral and luminescent properties of nanoclusters was studied for the first time. It has been shown that the luminescence of such clusters is radically different from the luminescence of undoped clusters and depends on the size of the nanocrystals. It is shown that the composition of particles participating in Förster transport depends on the moment of observation.

Full Text

Restricted Access

About the authors

D. S. Popkov

Moscow Institute of Physics and Technology

Email: pevtsov.dn@mipt.ru
Russian Federation, Dolgoprudny

D. N. Pevtsov

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS; Moscow Institute of Physics and Technology

Author for correspondence.
Email: pevtsov.dn@mipt.ru
Russian Federation, Chernogolovka; Dolgoprudny

L. M. Nickolenko

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS; Moscow Institute of Physics and Technology

Email: pevtsov.dn@mipt.ru
Russian Federation, Chernogolovka; Dolgoprudny

V. F. Razumov

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS; Moscow Institute of Physics and Technology

Email: pevtsov.dn@mipt.ru
Russian Federation, Chernogolovka; Dolgoprudny

References

  1. Razumov V. F. Role of collective interaction effects in nanoclusters of colloidal quantum dots. High Energy Chemistry, 2014, 48(b), 419.
  2. Masters B. R. Paths to Förster’s resonance energy transfer (FRET) theory. The European Physical Journal H, 2014, 39, 87-139.
  3. Nikolenko L. M., Pevtsov D. N., Gak V. Y., Nazarov V. B., Akimov A. V., Tovstun S. A., Razumov V. F. (2024). Delayed fluorescence of InP: Mn/ZnS nanocrystals. Journal of Photochemistry and Photobiology A: Chemistry, 448, 115298.
  4. R. Beaulac, P.I. Archer, S.T. Ochsenbein, D.R. Gamelin. Mn2+-doped CdSe quantum dots: New inorganic materials for spin-electronics and spin-photonics, Adv. Funct. Mater. 18 (2008) 3873–3891.
  5. R. Beaulac, P.I. Archer, D.R. Gamelin. Luminescence in colloidal Mn2+-doped semiconductor nanocrystals, J. Solid State Chem. 181 (2008) 1582–1589.
  6. M. Tanaka, J. Qi, Y. Masumoto. Comparison of energy levels of Mn2+ in nanosized- and bulk-ZnS crystals, J. Lumin. 87–89 (2000) 472–474.
  7. Shiliang Meia, Xian Weia, Dan Yanga, Danlu Sua, Wu Yanga, Guilin Zhanga, Zhe Hua, BoBo Yangb, Hanqing Daib, Fengxian Xiea, Wanlu Zhanga, Ruiqian Guo. Journal of Luminescence, 212 (2019), 264–270
  8. Brichkin, S. B., Tovstun, S. A., Spirin, M. G., Razumov, V. F. (2017). Förster resonance energy transfer in nanoclusters of InP@ ZnS colloidal quantum dots with dodecylamine ligand shells. High Energy Chemistry, 51, 455-461.
  9. Tovstun, S. A., Gadomska, A. V., Spirin, M. G., Razumov V. F. (2022). Extracting the homogeneous and inhomogeneous linewidths of colloidal quantum dots from the excitation-emission matrix. Journal of Luminescence, 252, 119420.
  10. Yuldasheva D. K., Pevtsov D. N., Gadomska A. V., Tovstun S. A. (2022). Kinetics of Nonradiative Energy Transfer between Close-Packed InP/ZnS Nanocrystals. High Energy Chemistry, 56(6), 399–410.

Supplementary files

Supplementary Files
Action
1. JATS XML
2. Fig. 1. Kinetic scheme of excitation transport in CT nanoclusters InP:Mn/Zn.

Download (93KB)
3. Fig. 2. Photoluminescent properties of InP:Mn/Zn CCTS of different sizes.

Download (145KB)
4. 3. Absorption (blue) and luminescence (red) spectra at an excitation wavelength of 425 nm CT InP:Mn/ZnS in hexane.

Download (140KB)
5. 4. The excitation–luminescence matrices of (a) a colloidal solution of CCT InP:Mn/ZnS and (b) a colloidal solution of nanoclusters obtained by aggregation of a colloidal solution of CCT InP:Mn/ZnS.

Download (189KB)
6. 5. Luminescence spectra of the solution (solid) and clusters (dotted) of the InP:Mn/ZnS CT at various excitation wavelengths.

Download (253KB)
7. 6. Time-resolved luminescence matrices of (a) solution and (b) Ni:Mn/Zn nanoclusters.

Download (188KB)
8. 7. Fluorescence spectra of the solution (solid) and clusters (dotted) of InP:Mn/ZnS CT at an excitation wavelength of 372 nm at different observation times.

Download (144KB)

Copyright (c) 2024 Russian Academy of Sciences