Barrier discharge conversion of gaseous olefins

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The oxidation of olefins С2–С4 in a barrier discharge in the presence of water has been investigated, with the formation of oxygen-containing compounds and various hydrocarbons С1–С5+ of limited and unsaturated structure being observed. The initial olefin’s molecular weight and structure have been found to exert a significant influence on the direction of the reaction. In the ethylene-propylene-butylene series, the proportion of oxygen-containing compounds increases from 28.1, 74.3 and 66.7 wt%, respectively. The oxidation of isobutene isomasalic aldehyde and acetone, with a content of 53 and 21 wt. %, respectively, primarily yields the formation of these compounds. In the case of the oxidation of butene-1 and butene-2, the predominant products are butanol-2, with a yield of up to 26 wt. %.

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作者简介

A. Ryabov

Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: a.y.ryabov@yandex.ru
俄罗斯联邦, Tomsk

S. Kudryashov

Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences

Email: a.y.ryabov@yandex.ru
俄罗斯联邦, Tomsk

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2. Fig. 1. Formation of oxygen-containing compounds (oxygenates) and hydrocarbons (●) during the oxidation of gaseous olefins with air, depending on its content in the initial mixture.

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3. 2. The group composition of the reaction products depending on the air content in the initial mixture with butane.

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4. 3. The composition and content of oxygen-containing compounds in the oxidation products of butenes at 90% of the air content in the initial mixture.

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