Barrier discharge conversion of gaseous olefins

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Abstract

The oxidation of olefins С2–С4 in a barrier discharge in the presence of water has been investigated, with the formation of oxygen-containing compounds and various hydrocarbons С1–С5+ of limited and unsaturated structure being observed. The initial olefin’s molecular weight and structure have been found to exert a significant influence on the direction of the reaction. In the ethylene-propylene-butylene series, the proportion of oxygen-containing compounds increases from 28.1, 74.3 and 66.7 wt%, respectively. The oxidation of isobutene isomasalic aldehyde and acetone, with a content of 53 and 21 wt. %, respectively, primarily yields the formation of these compounds. In the case of the oxidation of butene-1 and butene-2, the predominant products are butanol-2, with a yield of up to 26 wt. %.

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About the authors

A. Y. Ryabov

Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences

Author for correspondence.
Email: a.y.ryabov@yandex.ru
Russian Federation, Tomsk

S. V. Kudryashov

Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences

Email: a.y.ryabov@yandex.ru
Russian Federation, Tomsk

References

  1. Samoilovich V.G., Gibalov V.I., Kozlov K.V. // Physical Chemistry of Barrier Discharge. M: Moscow state university. 1989. 174 p.
  2. Suttikul T., Yaowapong-aree S., Sekiguchi H. et al. // Chem. Eng. Process. 2013. V. 70. P. 222–232.
  3. Tsolas N., Yetter R.A., Adamovich I.V. // Combust. Flame. 2017. V. 176. P. 462–478.
  4. Suttikul T., Tongurai C., Sekiguchi H., Chavadej S. // Plasma. Chem. Plasma Process. 2012. V. 32. P. 1169–1188.
  5. Sreethawong T., Suwannabart T., Chavadej S. // Plasma Chem. Plasma Process. 2008. V. 28. P. 629–642.
  6. Tiwari S., Caiola A., Bai X. et al. // Plasma Chem. Plasma Process. 2020. V. 40 P. 1–23.
  7. Xiong H., Zhu X., Lu S. et al. // Sci. Total Environ. 2021. V. 788. P. 147675.
  8. Lin H., Guan B., Cheng Q., Huang Z. // Energy Fuels. 2010. V. 24. P. 5418–5425.
  9. Kudryashov S.V., Ochered’ko A.N., Ryabov A.Yu., Shchyogoleva G. S. // Plasma Chem. Plasma Process. 2011. V. 31. P. 649–661.
  10. Ryabov A. Yu., Kudryashov S. V., Ochered’ko A. N., Dankovtsev G.O. // Chem. Sustain. Dev. 2021. V. 29. P. 180–184.
  11. Ryabov A.Yu., Kudryashov S.V., Ocheredko A.N. // High Energy Chemistry. 2022. V. 56. № 3. P. 245–250.
  12. Ryabov A.Yu., Kudryashov S.V. // High Energy Chemistry. 2023. V. 57. № 4. P. 327–331.
  13. Kudryashov S. Ryabov A. Shchyogoleva G. // J. Phys. D: Appl. Phys. 2016. V. 49. P. 025205.
  14. Fridman A. // Plasma Chemistry. NY: Cembridge University Press, 2012. 979 p.
  15. Janev R.K., Reiter D. // Physics of Plasmas. 2004. V. 11. P. 780.
  16. Cvetanovic R.J. // J. Phys. Chem. Ref. Data. 1987. V. 16. P, 261.
  17. Caracciolo A., Vanuzzo G., Balucani N. et al. // J. Phys. Chem. A. 2019. V. 123. P. 9934–9956.

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2. Fig. 1. Formation of oxygen-containing compounds (oxygenates) and hydrocarbons (●) during the oxidation of gaseous olefins with air, depending on its content in the initial mixture.

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3. 2. The group composition of the reaction products depending on the air content in the initial mixture with butane.

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4. 3. The composition and content of oxygen-containing compounds in the oxidation products of butenes at 90% of the air content in the initial mixture.

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