INTERACTION OF GOLD AND NICKEL NANOPARTICLES WITH MOLECULAR HYDROGEN AND CARBON MONOXIDE IN THE PRESENCE OF AN ELECTRIC FIELD

M V GRISHIN; Гришин М. В.; A K GATIN; Гатин А. К.; E K GOLUBEV; Голубев Е. К.; N. V. DOKHLIKOVA; Дохликова Н. В.; S. A. OZERIN; Озерин С. А.; S. YU. SARVADI; Сарвадий С. Ю.; I. G. STEPANOV; Степанов И. Г.; V. G. SLUTSKII; Слуцкий В. Г.; V. A. KHARITONOV; Харитонов В. А.; B. R. SHUB; Шуб Б. Р.

doi:10.31857/S0023291222600407

INTERACTION OF GOLD AND NICKEL NANOPARTICLES WITH MOLECULAR HYDROGEN AND CARBON MONOXIDE IN THE PRESENCE OF AN ELECTRIC FIELD

Authors: GRISHIN MV¹, GATIN AK¹, GOLUBEV EK², DOKHLIKOVA N.V.¹, OZERIN S.A.¹, SARVADI S.Y.¹, STEPANOV I.G.¹, SLUTSKII V.G.¹, KHARITONOV V.A.¹, SHUB B.R.¹
Affiliations:
1. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russia
2. Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, Moscow, Russia
Issue: Vol 85, No 1 (2023)
Pages: 19-27
Section: Articles
Submitted: 27.02.2025
Published: 01.01.2023
URL: https://gynecology.orscience.ru/0023-2912/article/view/671760
DOI: https://doi.org/10.31857/S0023291222600407
EDN: https://elibrary.ru/KEOADV
ID: 671760

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Abstract

A nanostructured gold–nickel coating has been synthesized on the surface of pyrolytic graphite. Its physicochemical properties have been studied by scanning tunneling microscopy and spectroscopy, Auger spectroscopy, mass spectrometry, and other methods. It has been found that the coating consists of clusters formed by gold and nickel nanoparticles. It has been shown that an electric field can inhibit or stimulate the adsorption of hydrogen on gold and the reduction of the oxidized surface of nickel nanoparticles with carbon monoxide. The mechanisms of the influence of the field on the chemical processes involving H2 and CO are different. Quantum-chemical simulation has made it possible to determine the values of the energy barriers for CO adsorption on nickel nanoparticles.

References

Roldan Cuenya B. Synthesis and catalytic properties of metal nanoparticles: size, shape, support, composition, and oxidation state effects // Thin Solid Films. 2010. V. 518. № 12. P. 3127. https://doi.org/10.1016/j.tsf.2010.01.018
Gerasimov G.N., Ikim M.I., Gromov V.F., Ilegbusi O.J., Trakhtenberg L.I. Chemical modification of impregnated SnO2–In2O3 nanocomposites due to interaction of sensor components // Journal of Alloys and Compounds. 2021. V. 883. P. 160817. https://doi.org/10.1016/j.jallcom.2021.160817
Wang X., Tang F., Qi X., Lin Z., Battocchi D., Chen X. Enhanced protective coatings based on nanopartic-le fullerene C60 for oil & gas pipeline corrosion mitigation // Nanomaterials. 2019. V. 9. № 10. P. 1476. https://doi.org/10.3390/nano9101476
Chopani S.M.H., Asadi S., Heravi M.M. Application of bimetallic and trimetallic nanoparticles supported on graphene as novel heterogeneous catalysts in the reduction of nitroarenes, homo-coupling, Suzuki-Miyaura and Sonogashira reactions // Current Organic Chemistry. 2020. V. 24. № 19. P. 2216. https://doi.org/10.2174/1385272824999200914111559
Keane M.A., Gomez-Quero S., Cardenas-Lizana F., Shen W. Alumina-supported Ni–Au: surface synergistic effects in catalytic hydrodechlorination // ChemCatChem. 2009. V. 1. № 2. P. 270. https://doi.org/10.1002/cctc.200900070
Yuan G., Louis C., Delannoy L., Keane M.A. Silica- and titania-supported Ni–Au: application in catalytic hydrodechlorination // J. Catal. 2007. V. 247. № 2. P. 256. https://doi.org/10.1016/j.jcat.2007.02.008
Wu Z., Zhao Z., Zhang M. Synthesis by replacement reaction and application of TiO2-supported Au–Ni bimetallic catalyst // ChemCatChem. 2010. V. 2. № 12. P. 1606. https://doi.org/10.1002/cctc.201000165
Cardenas-Lizana F., Gomez-Quero S., Jacobs G., Ji Y., Davis B.H., Kiwi-Minsker L., Keane M.A. Alumina supported Au–Ni: surface synergism in the gas phase hydrogenation of nitro-compounds // J. Phys. Chem. C. 2012. V. 116. № 20. P. 11166. https://doi.org/10.1021/jp3025528
Cardenas-Lizana F., Keane M.A. Gas phase selective hydrogenation over oxide supported Ni–Au // Phys. Chem. Chem. Phys. 2015. V. 17. № 42. P. 28088. https://doi.org/10.1039/c5cp00282f
Wei H., Wei X., Yang X., Yin G., Wang A., Liu X., Huang Y., Zhang T. Supported Au−Ni nano-alloy catalysts for the chemoselective hydrogenation of nitroarenes // Chinese Journal of Catalysis. 2015. V. 36. № 2. P. 160. https://doi.org/10.1016/S1872-2067(14)60254-0
Nikolaev S.A., Smirnov V.V. Synergistic and size effects in selective hydrogenation of alkynes on gold nanocomposites // Catal. Today. 2009. V. 147. P. S336. https://doi.org/10.1016/j.cattod.2009.07.032
Aguilar-Tapia A., Delannoy L., Louis C., Han C.W., Ortalan V., Zanella R. Selective hydrogenation of 1,3-butadiene over bimetallic Au–Ni/TiO2 catalysts prepared by deposition-precipitation with urea // J. Catal. 2016. V. 344. P. 515. https://doi.org/10.1016/j.jcat.2016.10.025
Chai M., Liu X., Li L., Pei G., Ren Y., Su Y., Cheng H., Wang A., Zhang T. SiO2-supported Au–Ni bimetallic catalyst for the selective hydrogenation of acetylene // Chin. J. Catal. 2017. V. 38. № 8. P. 1338. https://doi.org/10.1016/S1872-2067(17)62869-9
Ruppert A.M., Jedrzejczyk M., Potrzebowska N., Kazmierczak K., Brzezinska M., Sneka-Platek O., Sautet P., Keller N., Michel C., Grams J. Supported gold–nickel nano-alloy as a highly efficient catalyst in levulinic acid hydrogenation with formic acid as an internal hydrogen source // Catal. Sci. Technol. 2018. V. 8. № 17. P. 4318. https://doi.org/10.1039/C8CY00462E
Wang F., Zhang J.-C., Li W.-Z., Chen B.-H. Coke-resistant Au–Ni/MgAl2O4 catalyst for direct methanation of syngas // J. Energy Chem. 2019. V. 39. P. 198. https://doi.org/10.1016/j.jechem.2019.03.028
Chin Y.-H., King D.L., Roh H.-S., Wang Y., Heald S.M. Structure and reactivity investigations on supported bimetallic Au−Ni catalysts used for hydrocarbon steam reforming // J. Catal. 2006. V. 244. Iss. 2. P. 153. https://doi.org/10.1016/j.jcat.2006.08.016
Molenbroek A.M., Nørskov J.K., Clausen B.S. Structure and Reactivity of Ni−Au Nanoparticle Catalysts // J. Phys. Chem. B. 2001. V. 105. № 23. P. 5450. https://doi.org/10.1021/jp0043975
Grishin M.V., Gatin A.K., Dokhlikova N.V., Kirsankin A.A., Kulak A.I., Nikolaev S.A., Shub B.R. Adsorption and interaction of hydrogen and oxygen on the surface of separate crystalline gold nanoparticles // Kinetics and Catalysis. 2015. V. 56. № 4. P. 532. https://doi.org/10.1134/S0023158415040084
Grishin M.V., Gatin A.K., Sarvadii S.Y., Shub B.R. Study of adsorption and interaction of H2, O2, and CO on the surface of single gold nanoparticles and nickel by scanning tunneling microscopy // Nanotechnologies in Russia. 2017. V 12. № 11–12. P. 589. https://doi.org/10.1134/S1995078017060040
Gatin A.K., Grishin M.V., Sarvadii S.Y., Shub B.R. Interaction of gaseous reagents on gold and nickel nanoparticles // Russian Journal of Physical Chemistry B. 2018. V. 12. № 2. P. 317. https://doi.org/10.1134/S1990793118020069
Aragonès A.C., Haworth N.L., Darwish N., Ciampi S., Bloomfield N.J., Wallace G.G., Diez-Perez I., Coote M.L. Electrostatic catalysis of a Diels–Alder reaction // Nature. 2016. V. 531. P. 88. https://doi.org/10.1038/nature16989
Martín L., Molins E., Vallribera A. Tuning and enhancement of the Mizoroki–Heck reaction using polarized Pd nanocomposite carbon aerogels // New J. Chem. 2016. V. 40. Iss. 12. P. 10208. https://doi.org/10.1039/C6NJ02279K
Sarvadiy S.Y., Gatin A.K., Grishin M.V., Kharitonov V.A., Kolchenko N.N., Dokhlikova N.V., Shub B.R. Electric field–prevented adsorption of hydrogen on supported gold nanoparticles // Gold Bulletin. 2019. V. 52. № 2. P. 61. https://doi.org/10.1007/s13404-019-00253-1
Sarvadii S.Y., Gatin A.K., Kharitonov V.A., Dokhlikova N.V., Ozerin S.A., Grishin M.V., Shub B.R. Effect of CO molecule orientation on the reduction of Cu-based nanoparticles // Nanomaterials. 2021. V. 11. № 2. 279. https://doi.org/10.3390/nano11020279
Binnig G., Rohrer H., Berber C., Weibel E. Tunneling through a controllable vacuum gap // Appl. Phys. Lett. 1982. V. 40. № 2. P. 178. https://doi.org/10.1063/1.92999
Meyer E., Hug H.J., Bennewitz R. Scanning Probe Microscopy. Berlin: Springer, 2004.
Hamers R.J., Wang Y.J. Atomically-resolved studies of the chemistry and bonding at silicon surfaces // Chemical Reviews. 1996. V. 96. № 4. P. 1261. https://doi.org/10.1021/cr950213k
Hamers R.J., Tromp R.M., Demuth J.E. Surface electronic structure of Si (111)–(7 × 7) resolved in real space // Phys. Rev. Let. 1986. V. 56. № 8. P. 1972. https://doi.org/10.1103/PhysRevLett.56.1972
Schintke S., Messerli S., Pivetta M., Patthey F., Libioulle L., Stengel M., De Vita A., Schneider W.-D. Insulator at the ultrathin limit: MgO on Ag(001) // Phys. Rev. Let. 2002. V. 87. № 27. P. 276801. https://doi.org/10.1103/PhysRevLett.87.276801
Kovalevskii S., Dalidchik F., Grishin M., Kolchenko N., Shub B. Scanning tunneling spectroscopy of vibrational transitions // Appl. Phys. A. 1998. V. 66. P. S125. https://doi.org/10.1007/s003390051114
Irwin M.D., Buchholz D.B., Hains A.W., Chang R.P.H., Marks T.J. p -Type semiconducting nickel oxide as an efficiency-enhancing anode interfacial layer in polymer bulk-heterojunction solar cells // Proc. Natl. Acad. Sci. USA. 2008. V. 105. № 8. P. 2783. https://doi.org/10.1073/pnas.0711990105
Divi S., Chatterjee A. Generalized nano-thermodynamic model for capturing size-dependent surface segregation in multi-metal alloy nanoparticles // RSC Advances. 2018. V. 8. P. 10409. https://doi.org/10.1039/C8RA00945G
Dey S., Mehta N.S. Oxidation of carbon monoxide over various nickel oxide catalysts in different conditions: a review // Chemical Engineering Journal Advances. 2020. V. 1. 100008. https://doi.org/10.1016/j.ceja.2020.100008
Grishin M.V., Gatin A.K., Kharitonov V.A., Ozerin S.A., Sarvadii S.Yu., Shub B.R. Interaction of gases with single clusters of gold and copper-based nanoparticles in the presence of electric fields // Russian Journal of Physical Chemistry B. 2022. V. 16. № 2. P. 211. https://doi.org/10.1134/S199079312232001X
Vesecky S.M., Xu X., Goodman D.W. Infrared study of CO on NiO(100) // Journal of Vacuum Science & Technology A. 1994. V. 12. № 4. P. 2114. https://doi.org/10.1116/1.579146
Giannozzi P., Andreussi O., Brumme T., Bunau O., Buongiorno Nardelli M., Calandra M., Car R., Cavazzoni C., Ceresoli D., Cococcioni M., Colonna N., Carnimeo I., Dal Corso A., de Gironcoli S., Delu-gas P., DiStasio Jr. R.A., Ferretti A., Floris A., Fratesi G., Fugallo G., Gebauer R., Gerstmann U., Giustino F., Gorni T., Jia J., Kawamura M., Ko H.-Y., Kokalj A., Küçükbenli E., Lazzeri M., Marsili M., Marzari N., Mauri F., Nguyen N.L., Nguyen H.-V., Otero-de-la-Roza A., Paulatto L., Poncé S., Rocca D., Sabatini R., Santra B., Schlipf M., Seitsonen A.P., Smogunov A., Timrov I., Thonhauser T., Umari P., Vast N., Wu X., Baroni S. Advanced capabilities for materials modelling with Quantum ESPRESSO // J. Phys. Condens. Matter. 2009. V. 21. P. 395502. https://doi.org/10.1088/1361-648X/aa8f79
Perdew J.P., Burke K., Ernzerhof M. Generalized gradient approximation made simple // Phys. Rev. Lett. 1996. V. 77. №. 18. P. 3865.
Perdew J., Ruzsinsky A., Csonka G.I., Vydrov O.A., Scuseria G.E., Constantin L.A., Zhou X., Burke K. Restoring the density-gradient expansion for exchange in solids and surfaces // Phys. Rev. Lett. 2008. V. 100. № 13. P. 136406. https://doi.org/10.1103/PhysRevLett.100.136406
Vanderbilt D. Soft self-consistent pseudopotentials in a generalized eigenvalue formalism // Phys. Rev. B. 1990. V. 41. № 11. P. 7892. https://doi.org/10.1103/PhysRevB.41.7892